Subduction is not the end

Subduction is just the beginning. Stuck on the surface of the earth as we are, it’s easy to think that when oceanic lithosphere1 is destroyed when it vanishes into the mantle. But this is wrong. The more we manage to peer into the earth’s depths, the more clearly we see that subducted oceanic lithosphere is still down there. It’s arrival into the deep earth influences many things and sets of changes that in turn affect the surface.

Our growing understanding of what happens to oceanic lithosphere when it reaches the deep earth comes from the integration of a vast repertoire of scientific approaches. Physics, chemistry, mathematical modelling, high-pressure laboratory experiments, tiny grains in diamonds – all these things have something to tell us about the deep earth.

As in the deep oceans, so in the deep earth. We now know that both places are extremely varied environments, warped by extreme pressures, full of the weird and the exotic and some surprising relics from the past. Both are hard (or impossible) to visit, yet they still have influence over surface conditions.

A journey into the deep

This is the first of a series of posts on the deep earth. There’s a great mass of fascinating recent science out there that deserves to be better know. As a taster, let me tell you about lovely little Nature paper from 2005 that picks out the themes I hope to trace through future posts: how much of the deep earth is still mysterious, how we know what we know, the billion-year timescales and how the surface and depths are intimately linked.

In the paper David Dobson and John Brodholt (both, then as now, at University College, London) speculate that some distinctive parts of the deepest mantle are formed from subducted banded-iron formation.

Folded banded iron formation. Photo was not taken at the core-mantle boundary. Image from Wikipedia.

Seismic studies (tracing the shakings caused by earthquakes) have identified parts of the lowest mantle where earthquake waves pass through over 10% slower than expected. This means that these areas, known here as ultralow-velocity zones (ULVZs), must be in some way different – either they are made of different material or they are are at a different temperature to their surroundings.

Nobody knows what the ULVZs are made of, but our authors put the case that they contain large volumes of banded-iron-formation (BIF). Between 2.8 and 1.8 billion years ago photosynthetic organisms (probably bacteria) profoundly changed our planet’s atmosphere by producing vast quantities of Oxygen. One consequence was that ferric iron, dissolved in the ocean, bound with the Oxygen ‘waste’ and was precipitated out as solid minerals of magnetite and haematite. This process created vast volumes of marine sediments rich in iron. These banded iron formation deposits are found in rocks of this age from around the world.

Assuming this material was subducted what would happen and could it account for the properties of the ULVZs at the bottom of the mantle?  Tracing through the required steps, our authors show that BIF material would be dense enough to sink to the base of the mantle, able to separate out from the more normal material in the subducted plate and would not dissolve into the underlying iron-rich core. If these steps had occurred, then the material would match the measurable properties of the ULVZs.

Just because something is plausible, doesn’t make it true of course. Proving this link between ULVZs and BIFs definitively may never be possible. But one further clue exists: having an iron rich layer close to the edge of the core might help explain patterns of change in the length of the day we surface-dweller can observe.

The earth’s nutations are daily variations in its rotation. They are caused by the pull of the earth, sun and other bodies, but are also influenced by the degree to which the core and mantle spin independently or are coupled together. The outer core is liquid and the mantle solid, so they would be able to spin independently, but studies of nutations suggest there is some coupling – transfer of momentum – between them. If ULVZs are formed of BIFs and so very rich in iron, they would interact with the earth’s magnetic field causing electromagnetic coupling in a way that matches the observations.

It’s a mind-expanding idea. Sediments formed billions of years ago in a now alien atmosphere sit thousands of kilometres under our feet, subtly modulating the length of the day.

Deep cycles

When listening to a classical orchestra, most often we are paying attention to the high to middling frequency sounds – the violins, flutes and so on. The full experience – a live performance – is vastly enriched by the deepest, lowest frequency instruments. A full desk of double basses, or some bass clarinets make the air itself throb, producing a more physical, visceral and emotional experience2.

Our experience of living on this planet is enriched by our understanding of its cycles of change. The most frequent are most apparent: the year’s seasons; the carbon cycle; Milankovitch cycles that bring ice to sculpt the landscape. Subduction is one of the deepest, the slowest of them all – linking the familiar surface with the mysterious depths, it is the fundamental frequency in the orchestra of the earth.


The Nature paper is available here.

Dobson D.P. (2005). Subducted banded iron formations as a source of ultralow-velocity zones at the core–mantle boundary, Nature, 434 (7031) 371-374. DOI:

Categories: Deep earth, subduction

Paths across the Cheshire Peak

Driving west across the edge of the English Peak District is a good way to see how geology shapes landscape. Tracing the routes that cross it – feeling their shapes with a finger on a map or with your body as the car swings round bends – hints at how they are shaped by the landscape beneath, but also the intentions of the people who first made them. Paths across the Cheshire peak were shaped by dramatic changes across both human and geological history.

The new Buxton road winds below Shining Tor. © Copyright Jonathan Wakefield and licensed for reuse under this Creative Commons Licence

Roads in Derbyshire’s ‘White Peak’ are shaped by the limestone beneath; they sit in the bottom of ‘dales’ – steep gorges etched into rock – or wind across a bucolic landscape of green fields tessellated by white stone walls. But drive out of Buxton on the Macclesfield (“Cat and Fiddle”1) road and you suddenly enter a wilder world. Within a few feet, the stone walls at the side of the road turn from pale grey to a buff beige.  The landscape is brown and open, empty under a sky that is rarely entirely blue, mantled by peat bog and growing little but heather. You are entering one of the ‘Dark Peak’, one of the wild moors of northern England, the wuthering heights where Heathcliff roamed and Ted Hughes’ hawk roosts.

Further west, at the edge of the moors everything changes again – the Cheshire Plain appears laid out for inspection. On a clear day – or better still night – the view takes the breath away. The homes and lights of 3 million people twinkle and beguile. The depth of detail invites you to study, to pick out Jodrell Bank, flights descending into Manchester airport, Alderley Edge….

The Buxton road climbs up out of Macclesfield. Taken near Toll Bar Avenue.

The Buxton road climbs up out of Macclesfield. Taken near Toll Bar Avenue.

Drivers shouldn’t enjoy the spectacle: this road needs your full attention. It’s popular with motorcyclists for its many bends. Sadly some are total idiots, making the A537 one of Britain’s most dangerous roads. Their attitude to the area is not much different from many other modern travellers – this is a place to enjoy yourself in. Older generations – those who made this and other routes – had other motivations.



Early trade-routes

Some old routes over the high moors of northern England are know as the Saltways. The ‘wiches’ of Cheshire: Nantwich, Northwich and Middlewich, are towns based on salt. Thick layers sit deep within the Cheshire Basin, formed as a shallow sea was repeatedly evaporated under the Permian desert sun.

Salt has been produced in Cheshire since at least Roman times. An important commodity essential to food preservation (cheese! bacon!) it was transported across the country by salt traders (“salters”) who name attached to their routes. Below is my inference as to the route taken by salters through this area, passing through Saltersford Hall.

Trace of Salters way

Trace of Salters way in green. Macclesfield is the town on the left, Buxton on the right. The brown area in the middle is the moor

Buxton was a Roman town  and a direct line from the salt towns to there passes this way, but there is not good evidence it is that old. These routes are pre-industrial though, used by men and horses walking through the landscape, at the mercy of the elements. A reminder of how perilous this could be – hard to remember when speeding in a warm car – comes from an odd memorial stone on the route, that reads: “Here John Turner was cast away in a heavy snow storm in the night in or about the  year 1755. The print of a womans shoe was found by his side in the snow where he lay dead”

The front of the memorial stone. Source

 The modern age approaches

Even as John Turner grew cold in the snow,  the epoch-making2 Industrial Revolution was hotting up. Using new technology to centralise production in factories only make sense if you can then get your goods to the people who buy them – new forms of transport were an important factor.

The 18th Century – early on in the Industrial Revolution – innovation came in the form of many new roads, called turnpikes. These were independently financed toll roads, sanctioned by Acts of Parliament.

The first Macclesfield-Buxton toll road followed an old route, was ‘engineered by a blind man, John Metcalfe’, and opened in 1759. Initially controversial, it was opposed by some (local coal producers) but championed by the new industrialists.

Old Buxton road in blue, new road in red. Route over Shining Tor in brown.

Old Buxton road in blue, new road in red. Route over Shining Tor in brown.

This road and the salters way are both direct but steep. This is ideal when moving goods with pack horses, but horse-drawn wagons work better with more gradual slopes, even if the route is longer. By the dawn of the 19th Century, new road-building techniques had emerged that cut into the hillside to make wider carriage-ways that avoided steep slopes even over hilly terrain.

New and old Buxton roads cross the far hillside. Cat and Fiddle pub right hand skyline

New and old Buxton roads converge on the far hillside. The Cat and Fiddle pub is on the right hand skyline

In 1808, a new Eddisbury bypass just above Macclesfield was built by the famous engineer Thomas Telford, the “Colossus of Roads”. In 1821 the rest of the Macclesfield-Buxton road was modified with new winding flatter routes and a pub for the weary. The new road is wider than the old and climbs more gradually. To achieve this is has many bends, which attract the loonies in leather on their motorcycles.

A new ancient road

The transition from White to Dark peak, as you go east from Buxton is dramatic to us, but the incoming darkness would have been felt much more keenly by the Carboniferous inhabitants. The sparkling tropical seas where trilobites frolicked in crinoid forests were suddenly snuffed out by the arrival of massive amounts of sand and mud. Rocks made from the remains of life are replaced by those where fossils have to be sought out – traces in sand, crushed shells in rare marine muds or eventually, coal.

The most modern path across the Peak is also the most ancient. Walking across these hills for pleasure is extremely popular and paths easily cut into the soft peat. The most popular routes are now paved with big slabs of the local sandstone – along Shining Tor there are hundreds of them. Covered in ripples and the traces of burrowing bivalves, walking along these makes you feel like you are on a sandy shore 300 million years ago.


Slabs of sandstone along Shining Tor


Ancient ripples

Ancient ripples

"Lockeia" - traces of burrows from bivalves

“Lockeia” – traces of burrows from bivalves

Categories: England, landscape, sediments

A new paradigm for Barrovian metamorphism?

George Barrow

George Barrow (image via BGS)

The phrase ‘new paradigm’ is a little shop-worn but it still catches the eye. To see it used in a “discussion and reply” on a dry-looking metamorphic petrology paper is really something unusual. Tracing through these articles really shows how metamorphic petrology can get to the heart of understanding what happens in the core of mountain belts.

The example of “discussion and reply”1 I’m discussing here is truly remarkable. Everyone is terribly polite and there is lots of new data and ideas contained that shed light on a classic area for the understanding of metamorphism. It also illustrates the perils and challenges of interpreting complex rocks that formed in the heart of an ancient mountain.

A paper worth discussing

The original paper, entitled ‘Metamorphic P–T and retrograde path of high-pressure Barrovian metamorphic zones near Cairn Leuchan, Caledonian orogen, Scotland’ is by Kasumaza Aoki of Tokyo, Brian Windley of Leicester and others. It studies metamorphic rocks from the Scottish Highlands. You’ve heard of Barrovian metamorphism, (if not, get thee hence), this is the type locality, where George Barrow first identified zones of rock defined by particular ‘index’ minerals.

Sample of Cairn Leuchan Gneiss, collect by George Barrow himself. Garnet, plagioclase, Hornblende (brown), pyroxene (green).

Sample of Cairn Leuchan Gneiss, collected by George Barrow himself! Garnet, plagioclase, hornblende (brown), pyroxene (green). From BGS, sample S8146

Barrovian metamorphism is typical of mountain belts. It’s thought to be caused  by thrusting and stacking of rock slices within a growing mountain belt, that buries and heats up the rocks within it – causing metamorphism. This model is simple, classic and perhaps wrong. Our original paper looks at a slice of high grade rocks from the hottest, sillimanite zone. Detailed metamorphic petrology shows that “the rocks underwent high-pressure granulite facies metamorphism at P = c. 1.2–1.4 GPa and T = c. 770–800 °C followed by amphibolite facies metamorphism at P = c. 0.5–0.8 GPa and T = c. 580–700 °C”.

The later metamorphism is pretty standard for the area, but the earlier high pressure phase is unusual, suggesting these rocks were buried much deeper than previously thought. Our authors conclude that high-grade Barrovian metamorphism is retrograde, the metamorphic minerals formed as the rocks moved back towards the surface, masking an earlier deeper phase. They also suggest that the measured high-pressure metamorphism was also formed *on the way up* and that these rocks (perhaps all rocks in the area, there’s evidence nearby at Tomatin) had previously been down to eclogite or blue-schist depths.

If this paper were science journalism (or course it isn’t) you could accuse it of ‘burying the lede’ – the abstract focuses purely on what they proved. The major implications of their results are made much more explicit in the Discussion by Daniel Viete and others. S98121XPL


BGS sample S98121. Garnet amphibolite from Tomatin. First XPL then PPL. Relict high-pressure eclogitic garnet breaking down to plagioclase and amphibole as it moved towards the surface.

“Interesting, but maybe it’s actually….”

The discussion (by Daniel Viete, whose research I’ve written about before and others) argues against the original papers conclusions, using two lines of attack. Firstly they focus on how hard it would be to get rocks so hot, so early in the orogeny2. Other high pressure rocks in the Grampian Orogeny are much colder (e.g. blueschists in Clew Bay, Ireland). From dating, we know that the Scottish rocks were metamorphosed relatively quickly (18 million years or less). Indeed Viete has already written about the difficulty of getting rocks in this area hot enough, quick enough. This was for the well known temperatures. The problem is even greater for Aoki’s earlier deeper and hotter phase. Listing all the ways these rocks could have been heated up (mantle melts, radioactive heating, mechanical heating, already hot from rifting) they conclude that the early measured temperatures are not possible.

Secondly they describe the local geology in terms of networks of long-lived shear zones, that interleave Dalradian sediments with older basement rocks. They also provide a date of 1 billion years (much than the Ordovician age of Barrovian metamorphism) from the Cowhythe Gneiss at Portsoy, a nearby patch of high grade rocks. In conclusion, the early high-pressure metamorphism that Aoki and others describes is from an entirely different orogeny and found only in odd slices of older rock.


BGS sample S94156.  Garnet amphibolite from Tomatin. Intergrowths of plagioclase and amphibole – formed by decompression of an eclogite?

“With respect, no it’s not. Plus we’ve got a brand new paradigm!”

In their reply, Aoki and others defend their conclusions. Their rocks are not basement and are totally different from the Cowhythe Gneiss. Plus, old ages can often be ‘inherited’ – dated zircons may contain old ages since the crystal was a ‘detrital’ grain within the sediment that was later metamorphosed. They then turn to their explanation for their results. Acknowledging that “a reply to a comment is not the correct place to propose an entirely new paradigm for such a classic orogen” they nevertheless provide a brief overview, promising to “present our model more fully in a future publication“.

They start with the well-known enigma of how to provide the heat for Barrovian metamorphism. Modelling suggests that stacking rocks and waiting for them to heat up (the classic England & Houseman model) actually takes 50 million years. Viete has previously proposed the heat came in via advection via hot fluids. Aoki’s model proposes “the extrusion of a major wedge of hot deep eclogite which was exhumed up a subduction channel several tens of kilometres thick“.


What they are proposing is that hot rocks within  the subduction zone, perhaps 40 km below the slowly heating orogenic wedge, broke free and was squeezed up into it, heating the wedge and causing rapid Barrovian metamorphism. This would be an extremely dramatic thing and is a radical departure from existing models for this orogeny, which is itself the ‘type locality’ for all instances of Barrovian metamorphism. Aoki refer to one earlier paper by a group from Cambridge that propose a similar mechanism for the Alps. The Alpine eclogite wedge is still clearly eclogite forming a discrete unit within other nappes. It’s not (yet) clear how Aoki’s traces of earlier high pressure minerals in an relatively homogenous Dalradian correspond to this.

What does it all mean?

For what it’s worth, I’m a little sceptical – my headline follows Betteridge’s Law – but we’ll have to wait for the paper that properly presents the new model before we can judge.

One thing that strikes me is how much Wheeler’s paper on the importance of stress throws doubt on this work. Tales of packages of rock squeezing 10s of kilometres up into an orogeny puts a lot of weight on the traces of high pressure metamorphism that are the main evidence. Explaining high pressures in terms of localised stress starts to seem like a much simpler explanation.

This is a fascinating series of papers3. It highlights how vital metamorphic petrology is to understanding mountain building processes. George Barrow first identified his zones over a hundred years ago and the Scottish Highlands have been intensely studied ever since, yet we still don’t fully understand how they formed.

The fact these papers are hidden behind a paywall is in stark contrast to the pictures I’ve used. All come from the British Geological Survey who have made them free to all. The depth of coverage is fabulous – I’ve been able to find images from the key localities mentioned in the papers within minutes. This illustrates the power of open data rather nicely – if only we could all find scientific papers as easily.


The original paper.
AOKI K., S. MARUYAMA & S. OMORI (2013). Metamorphic P–T conditions and retrograde path of high-pressure Barrovian metamorphic zones near Cairn Leuchan, Caledonian orogen, Scotland, Geological Magazine, 151 (03) 559-571. DOI:

The discussion and reply.
Viete D.R. & S. A. Wilde (2014). Discussion of ‘Metamorphic P–T and retrograde path of high-pressure Barrovian metamorphic zones near Cairn Leuchan, Caledonian orogen, Scotland’, Geological Magazine, 151 (04) 755-758. DOI:

The Alpine paper
Smye A.J., Tim J.B. Holland, Randall R. Parrish & Dan J. Condon (2011). Rapid formation and exhumation of the youngest Alpine eclogites: A thermal conundrum to Barrovian metamorphism, Earth and Planetary Science Letters, 306 (3-4) 193-204. DOI:

An old paper on the Tomatin ‘eclogites’  

Categories: eclogites, metamorphism, mountains, Scotland, tectonics

Metamorphic petrology: under pressure and getting stressed?

High pressure (HP) terranes are areas containing eclogites and other eclogite-facies rocks found within many mountains belts, including the Himalaya and the Alps. HP rocks were metamorphosed at extreme pressures, up to 3 or even 4 billion Pascals (or GPa. Atmospheric pressure is 0.0001 GPa). Based on the assumption that metamorphic pressure relates to depth of burial, these rocks have been to depths below the base of the crust. Explaining how to bury rocks so deeply, and then bring them back again, is a tricky problem.

Two parallel threads of research are challenging the assumption that high metamorphic pressures relate simply to depth of burial. Both seek to show that metamorphic reactions, and the patterns of minerals that they form, are also influenced by the squeezing and squashing rocks receive as they flow deep within the earth.

Alps 025

High pressure rocks looking moody and gorgeous. Photo of the Internal zones of the Alps from John Wheeler.

A little theory (please, don’t get stressed)

Metamorphic petrology is the art and Science of calculating the conditions under which metamorphic minerals form – I’ve written extensively about it already1. It has its basis in an understanding of the thermodynamics of the reactions that form minerals, which depend (among other things) on the temperature and pressure at the time. The lithostatic pressure that affected the rock is assumed to be caused by the weight of the column of rock overhead, following Pascal’s law2. With some assumptions as to the density of that rock, pressure can be converted into depth.

Earth scientists who study the structure of deeply buried rocks look instead at the patterns that the minerals form: fabrics, lineations, folds and the like. They have a different way of looking at the way rocks are squashed. Theories of rock deformation talk about stress, often visualised as arrows in 3 dimensions. If the stress is isotropic – equal in all three dimensions – then it is conceptually the same as lithostatic pressure. In contrast, differential stress is where the arrows are different sizes. Differential stress drives deformation – the rocks change shape.

Time for an analogy. Lithostatic pressure is like water pressure. Deep hot rocks flow like a fluid (slowly) and so the stress is equal in all directions. Rocks keep the same shape, but are put under tremendous pressure. It’s the same as putting a styrofoam cup into deep water.


Sytrofoam cup crushed at 600m ocean depth. Image from Gina Trapani under Creative Commons.

Differential stress is like putting the cup between the grabbers of the submersible. Squeezing in only one direction will change the shape of the cup.

Now we’re ready to look at the two challenges to the depth-pressure connection.

Challenge 1 – High levels of differential stress exist in the crust

Metamorphic petrologists who argue that high pressures are caused by deep burial believe that the effects of differential stress are unimportant. These rocks are usually extremely deformed, but they were hot and soft – by flowing easily they prevented high differential stresses from building up. In a similar way, as every toddler learns, you can’t squeeze jelly hard with your hands, because it just flows out of your fist.

Some scientists, with an interest in the European Alps, disagree. Neil Mancktelow argues that the effects of differential stress (he uses the basically equivalent similar term ‘tectonic overpressure’3 ) can be dramatic. Mathematical modelling of conditions within a confined channel (like a subduction zone) gives ‘overpressure’ of “perhaps even a few GPa”. Rocks that formed under these conditions would yield high pressure minerals but may not have been buried very deep.

At this years EGU meeting Stefan Markus Schmalholz, Yuri Podladchikov, and Sergei Medvedev used computer modelling of the Alpine orogeny, and other arguments to suggest that Alpine high-pressure eclogites need not have been deeply buried, but instead their distinctive minerals formed under conditions of tectonic overpressure.


Folded layers from eclogite facies rocks in Norway. Photo from John Wheeler

Challenge 2 – John Wheeler’s recent paper in Geology

Computer models are extremely useful, but only as good as the assumptions made in them. Alone they will always have their critics. John Wheeler, a professor at Liverpool University has fingers in many pies: metamorphism;  structural geology; field-based studies; laboratory work… He takes a different approach to also puts the assumption that we can apply Pascal’s law under intense pressure 4.

In a recent open source paper in Geology he combines 2 pieces of theory. The first is from thermodynamics as used in metamorphic petrology. The second is an equation relating stress to the phenomena of pressure solution (that can form cleavage in slaty rocks).  Both are concerned with the movement of atoms to grow new minerals and neither is controversial. He converts both into terms of chemical potential and combines them to link differential stress to standard metamorphic reactions.

Applying uncontroversial values for differential stress (e.g. 50 MPa, or 1/40th of the levels Mancktelow proposes) to a standard metamorphic reaction he shows that they shift by up to 500MPa – equivalent to 15km of lithostatic pressure.

This is an extremely dramatic result from a provocative paper, as John Wheeler himself acknowledges. Metamorphic rocks are almost always deformed, sometimes dramatically so. If both approaches are correct, then putting differential stresses of Manckletow levels into John Wheeler’s equations suggests any estimates of depth of metamorphism are open to challenge. Maybe eclogites never left the crust after all?

metagabbro deformed and recrystallizing to new minerals at the same time (from Alps).

Metagabbro deformed and recrystallizing to new minerals at the same time (sample from Alps image from John Wheeler).

Where are we now?

John Wheeler  expects some  “turbulent interactions in the next few years”.  I’m sure there are  metamorphic petrologists writing their replies to his paper right now. But assuming they can’t find some fundamental flaw he hasn’t spotted (extremely unlikely, I’d say), metamorphic petrology is facing a very big challenge.

This seems like bad news. Much work on metamorphic petrology is put to work refining tectonic models by building P-T-t paths that track metamorphic rocks as they are buried and return to the surface. The error bars on these estimates were big enough already – now a entire literature of estimates that ignore differential stress are thrown into question.

But let’s think positively. Might there be ways to disentangle the effects of lithostatic pressure and differential stress? Might there be ways to get even more information out of deformed metamorphic rocks? John Wheeler certainly thinks so and he aims to get there by integrating detailed studies of rock samples with laboratory experiments.

Big advances in Science often give us new ways to understand evidence that previously didn’t make sense. Studies of metamorphism from the classic locality of the Scottish Highlands (e.g. Viete et al 2011) have noted that the highest grades of metamorphism occur within shear zones. They tried to explain this in terms of the flow of hot fluids, but maybe the answer is simpler: stressing rocks really does cause them to grow different suites of metamorphic minerals.


Mancktelow N.S. (2008). Tectonic pressure: Theoretical concepts and modelled examples, Lithos, 103 (1-2) 149-177. DOI:

Wheeler J. (2014). Dramatic effects of stress on metamorphic reactions, Geology, DOI:

Viete D.R., G. S. Lister & I. R. Stenhouse (2011). The nature and origin of the Barrovian metamorphism, Scotland: diffusion length scales in garnet and inferred thermal time scales, Journal of the Geological Society, 168 (1) 115-132. DOI:

Categories: eclogites, metamorphism, mountains, subduction, tectonics